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Reporting a hazardous materials incident by phone to the National Response Center is crucial because this center is specifically designated to receive reports of hazardous material spills and incidents. The National Response Center operates as a federal point of contact for such reports, ensuring that necessary information can be rapidly disseminated to appropriate federal and state agencies for a coordinated response. This prompt reporting is essential to manage risks effectively, ensure public safety, and facilitate a proper cleanup process.

While local emergency services, the Environmental Protection Agency, and the Department of Transportation are all important entities in managing hazardous material situations, they may not be the most immediate point of contact in the event of an incident. The National Response Center serves as the first notification framework, allowing for swift action and subsequent notifications to be handled appropriately by local or other relevant agencies.